课题组主页：https://www.x-mol.com/groups/Chen-Tieqiao

研究方向:主要围绕有机磷化合物的绿色合成，惰性化学键活化，生物质的转化，药物与材料功能分子设计合成展开工作。

讲授课程:化工原理I，化工原理II，化学反应工程，高年级研讨课，有机化学实验，有机化学。

学术兼职:中国化学会会员，中国化工学会会员，永利集团科学技术协会委员，海南省生态环境厅突发环境事件应急专家，百度百科词条评审专家，海南省科技厅自然科学基金（重点研发计划）结题评审专家

教育部学位论文评审专家，科技部科技创新领军人才项目函评专家，国家自然科学基金委项目函评专家，《当代化工研究》编委，《精细化工》期刊青年编委，《General Chemistry》编委，

《Molecules》客座编辑，《Frontiers in Chemistry》客座编辑，《Applied Organometallic Chemistry》客座编辑，《Heteroatom Chemistry》Academic Editor，

浙江扬帆新材料股份有限公司顾问，海南万特制药有限公司首席科学家

学术成就:目前承担国家自然科学基金（面上基金）1项（原材料与化工学院历史上的第一个面上项目），国家自然科学基金（地区基金）1项，国家自然科学基金（青年基金）1项，海南省重点研发计划1项，海南省自然科学基金面上项目1项，湖南省自然科学基金（青年基金）1项。自2011年以来，以第一作者和通讯作者身份在J. Am. Chem. Soc. 4篇（2018年发表的JACS是以海南省科研机构为第一单位的第一篇，现今仅两篇），Angew. Chem. Int. Ed. 2篇等高水平国际期刊发表SCI论文80多篇。论文总被引2900多次，H-index为28。撰写Wiley书籍1章。

科研项目:[1] 酸/碘协同催化惰性酰胺C-N键的活化与转化研究，22261015，国家自然科学基金，33万，2023-2026，主持。

[2] 过渡金属催化酰胺C-N键活化与官能团化反应的研究，21871070，国家自然科学基金，66万，2019-2022，主持。

[3] 过渡金属催化惰性C-O键官能团化反应及其机理研究，21403062，国家自然科学基金，26万，2015-2017，主持。

[4] 有机磷功能化学品的绿色制造，XTCX2022STA01，永利集团协同创新中心A类项目（海南省重大），海南省科技厅，400万，2022-2025，主持。

[5] 羧酸类药物的羧基改性与生物活性研究，ZDYF2020168，海南省重点研发计划，80万，2020-2022，主持。

[6] 过渡金属催化C-H/P-H键脱氢偶联构建C-P键的研究，2015JJ3039，湖南省自然科学基金青年基金，4万，2015-2017，主持。

[7] 利用过渡金属催化脱氢偶联策略构建P-Z键的研究，219MS005，海南省自然科学基金面上项目，10万，2019-2020，主持。

[8] 永利集团C类高层次人才引进经费，300+250万，主持。

[9] 硫、磷化合物的绿色合成技术开发，HD-KYH-2023031,浙江杨帆新材料股份有限公司，60万，202303-202603，主持。

[9] 过渡金属催化脱氢偶联反应构建P-Z键的研究，国家自然科学基金，67万，2016-2019，第一参与。

[10] 末端炔烃交叉偶联反应的精密控制及机理研究，国家自然科学基金，66万，2016-2019，第一参与。

[11] 基于“金属有机骨架体”的生物-化学催化体系的建立和催化串联反应性能研究，国家自然科学基金，66万，2016-2019，第一参与。

论著专利:[1] Zuo D, Wang Q, Liu L, Huang T, Szostak M,* Chen T Q.* Highly Chemoselective Transamidation of Unactivated Tertiary Amides by Electrophilic N–C(O) Activation via Amide-to-Acyl Iodide Re-Routing. Angewandte Chemie International Edition, 2022, 61, e202202794.

[2] Chen T Q, Zhao C-Q, Han L-B.* Hydrophosphorylation of Alkynes Catalyzed by Palladium: Generality and Mechanism. Journal of the American Chemical Society, 2018, 140, 3139–3155.

[3] Zhu Y Y, Chen T Q,* Li S, Shimada S, Han L-B.* Efficient Pd-Catalyzed Dehydrogenative Coupling of P(O)H with RSH: a Precise Construction of P(O)-S Bonds. Journal of the American Chemical Society, 2016, 138, 5825–5828.

[4] Yang J, Chen T Q,* Han L-B.* C-P Bond-Forming Reactions via C-O/P-H Cross Coupling Catalyzed by Nickel. Journal of the American Chemical Society, 2015, 137, 1782-1785.

[5] Chen T Q,* Han L-B.* Nickel-Catalyzed C-O/C-H Cross-Coupling Reactions for C-C Bond Formation. Angewandte Chemie International Edition, 2015, 54, 8600-8602.

[6] Shen R W,b† Chen T Q,a† Zhao Y L, Qiu R H, Zhou Y B, Yin S F,* Wang X B, Goto M, Han L-B.* Facile Regio- and Stereoselective Hydrometalation of Alkynes with a Combination of Carboxylic Acids and Group 10 Transition Metal Complexes: Selective Hydrogenation of Alkynes with Formic Acid. Journal of the American Chemical Society, 2011, 133, 17037-17044 (†:并列第一作者, 第一单位第一作者).

[7] Xue Liu, Xinyi Li, Long Liu, Tianzeng Huang, Wen-Hao Chen, Michal Szostak*, Tieqiao Chen*, Pd/Cu-Catalyzed Synthesis of Internal and Sila-Ynones by Direct Selective Acyl Sonogashira Cross-Coupling of Carboxylic Acids with Terminal Alkynes. ACS Catalysis, 2023, 13,5819-5827.

[8] Liguang Gan, Tianhao Xu, Qihang Tan, Mengjie Cen, Lingling Wang,  Jingwei Zhao, Kuang Liu, Long Liu, Wen-Hao Chen, Li-Biao Han,* Jacek E. Nycz,* and Tieqiao Chen*, Metal-Free Highly Chemo-Selective Bisphosphorylation and Deoxyphosphorylation of Carboxylic Acid. Chemical Science, 2023, 14,5519-5526.

[9] Zhang M-Z,* Liu L, Gou Q, Wang Q, Li Y, Li W-T, Luo F, Yuan M, Chen T Q,* He W-M.* Synthesis of Hydroxyl-Containing Oxindoles and 3,4-Dihydroquinolin-2-ones through Oxone-Mediated Cascade Arylhydroxylation of Activated Alkenes. Green Chemistry, 2020, 22, 8369-8374.

[10]  Zhang M-Z,* Wang P, Liu H-Y, Wang D,* Deng Y, Bai Y-H, Luo F, Wu W-Y, Chen T Q.* Metal-Catalyst-Free One-Pot Aqueous Synthesis of trans-1,2-Diols from Electron-Deficient α,β-Unsaturated Amides via Epoxidation Using Oxone as a Dual Role Reagent. ChemSusChem, 2023, DOI: 10.1002/cssc.202300583.

[11] Zhang J-S, Liu L., Chen T Q,* Han L-B. Cross-Dehydrogenative Alkynylation: A Powerful Tool for the Synthesis of Internal Alkynes. ChemSusChem 2020, 13, 4776-4794.

[12] Liu X, Liu L, Huang T, Zhang J, Tang Z, Li C. Chen, T Q,* Trifluoromethylation of Benzoic Acids: An Access to Aryl Trifluoromethyl Ketones. Organic Letters, 2021, 23, 4930-4934.

[13] Li X, Liu L, Huang T, Tang Z, Li C, Li W, Zhang T, Li Z, Chen T Q.* Palladium-Catalyzed Decarbonylative Sonogashira Coupling of Terminal Alkynes with Carboxylic Acids. Organic Letters, 2021, 23, 3304-3309.

[14] Yu W Q, Liu L, Huang T Z, Zhou X B, Chen T Q,* Palladium-Catalyzed Decarbonylative Heck Coupling of Aromatic Carboxylic Acids with Terminal Alkenes. Organic Letters, 2020, 22, 7123-7128.

[15] Li Z, Liu L, Xu K, Huang T, Li X, Song B, Chen T Q.* Palladium-Catalyzed N-Acylation of Tertiary Amines by Carboxylic Acids: A Method for the Synthesis of Amides. Organic Letters, 2020, 22, 5517-5521.

[16] Liu L, Zhu D, Liu M, Zhou Y, Chen T Q,* Palladium-Catalyzed Decarbonylative Alkynylation of Amides. Organic Letters, 2018, 20, 2741-2744.

[17] Zhang J-S, Chen T Q,* Zhou Y, Yin S-F, Han L-B.* Catalytic sp3C-CN Bond Cleavage: Ni-Mediated Phosphorylation of Alkylnitriles. Organic Letters, 2018, 20, 6746-6749.

[18] Zhang J Q, Chen T Q,* Zhang J.-S., Han L.-B.* Silver-Free Direct Synthesis of Alkynylphosphine Oxides via spC-H/P(O)-H Dehydrogenative Coupling Catalyzed by Palladium. Organic Letters, 2017, 19, 4692-4695.

[19] Xiao J, Chen T Q,* Han L-B.* Nickel-Catalyzed Direct C-H/C-O Cross Couplings Generating Fluorobenzenes and Heteroarenes. Organic Letters, 2015, 17, 812–815.

[20] Zhao Y L, Chen T Q,* Han D Q, Zhao C-Q,* Han L-B.* Facile Base-Mediated Redox Transformation: An Efficient Strategy for the Synthesis of α Acyloxyphosphoryl Compounds. Organic Letters, 2014, 16, 6152-6155.

[21] Xi X X, Chen T Q,* Zhang J-S, Han L-B. Efficient and Selective Hydrogenation of C-O Bonds with a Simple Sodium Formate Catalyzed by Nickel. Chemical Communications, 2018, 54, 1521-1524.

[22] Xiao J, Yang J, Chen T Q,* Han L-B.* Nickel-Catalyzed Synthesis of (E)-Olefins from Benzylic Alcohol Derivatives and Arylacetonitriles via C-O Activation. Chemical Communications, 2016, 52, 2157-2160.

[23] Yang J, Xiao J, Chen T Q,* Yin S-F,* Han L-B.* Efficient Nickel-catalyzed Phosphinylation of C-S Bonds Forming C-P Bonds. Chemical Communications, 2016, 52, 12233-12236.

[24] Zhang J-S, Chen T Q,* Yang J, Han L-B.* Nickel-Catalysed P-C Bond Formation via P-H/C-CN Cross Couplings. Chemical Communications, 2015, 51, 7540-7542.

[25] Yang J, Chen T Q,* Zhou Y B, Yin S F, Han L-B.* Palladium-Catalyzed Dehydrogenative Coupling of Terminal Alkynes with Secondary Phosphine Oxides. Chemical Communications, 2015, 51, 3549-3551.

[26] Chen T Q, Guo C C,* Goto M, Han L -B.* A Brønsted acid-catalyzed generation of palladium complexes: efficient head-to-tail dimerization of alkynes. Chemical Communications, 2013, 49, 7498-7500.

[27] Xiao J, Yang J, Chen T Q,* Han L-B.* Nickel-Catalyzed α-Benzylation of Arylacetonitriles via C-O Activation. Advanced Synthesis & Catalysis, 2016, 358, 816-819.

[28] Chen H, Liu L, Huang T, Chen J,* Chen T Q.* Direct Dehydrogenation for the Synthesis of ,-Unsaturated Carbonyl Compounds. Advanced Synthesis & Catalysis, 2020, 362, 3332-3346.

[29] Xiang K, Zhang S, Liu L, Huang T, Tang Z, Li C, Xu K, Chen T Q.* Tunable C-H Arylation and Acylation of Azoles with Carboxylic Acids by Pd/Cu Cooperative Catalysis. Organic Chemistry Frontiers, 2021, 8, 2543-2550.

[30] Zhang M-Z,* Tian J, Yuan M, Peng W-Q, Wang Y-Z, Wang P, Liu L, Gou Q, Huang H, Chen T Q.* Visible Light-Induced Aerobic Dioxygenation of α,β-unsaturated amides/Alkenes toward Selective Synthesis of β-Oxy Alcohols Using Rose Bengal as a Photosensitizer. Organic Chemistry Frontiers, 2021, 8, 2215-2223.

[31] Liu M, Chen T Q,* Yin S F.* Copper-Catalysed Aerobic Oxidative Esterification of N-Heteroaryl Methanes with Alcohols. Catalysis Science & Technology, 2016, 6, 690-693.

[32] Liu M, Chen T Q,* Zhou Y B, Yin S F.* Transition Metal-Free Oxidative ortho-Acylation of Phenols with N-Heteroarylmethanes via Double C-H Activation. Catalysis Science & Technology, 2016, 6, 5792-5796.

[33] Chen X L,† Chen T Q,† Ji F Y, Zhou Y B,* Yin S-F.* Iron-Catalyzed Aerobic Oxidative Functionalization of sp3C-H Bonds: a Versatile Strategy for the Construction of N-Heterocycles, Catalysis Science & Technology, 2015, 5, 2197-2202 (†:并列第一作者).

[34] Chen X L,† Chen T Q,† Li Q, Zhou Y B, Han L-B, Yin S-F.* Copper-Catalyzed Aerobic Oxidative Inert C-C and C-N Bond Cleavage: A New Strategy for the Synthesis of Tertiary Amides. Chemistry - A European Journal, 2014, 20, 12234-12238 (†:并列第一作者).

[35] Dang Q, Chen J, Li T, Liu L, Huang T, Li C, Chen T Q, Palladium-Catalyzed Decarbonylative Annulation of 2-Arylbenzoic Acids with Internal Alkynes toward Phenanthrenes. The Journal of Organic Chemistry, 2023, DOI: 10.1021/acs.joc.3c01077

[36] Xu, T; Zhou, X; Xiao, X; Yuan, Y; Liu, L; Huang, T; Li, C; Tang, Z; Chen, T Q* Nickel-Catalyzed Decarbonylative Thioetherification of Carboxylic Acids with Thiols，The Journal of Organic Chemistry, 2022, 87, 8672-8648.

[37] Xu T, Li W, Zhang K, Han Y, Liu L, Huang T, Li C, Tang Z, Chen T Q.* Palladium-Catalyzed Decarbonylative Cyanation of Carboxylic Acids with TMSCN. The Journal of Organic Chemistry, 2022, 87, 11871-11879.

[38] Tang Y, Liu K, Zhang J, Liu L,* Huang T, Li C, Tang Z, Chen T Q.* Palladium-Catalyzed Stereoselective Difunctionalization of Bicyclic Alkenes with Organoammonium Salts and Organoboronic Compounds. The Journal of Organic Chemistry, 2021, 86, 11937-11947.

[39] Zhang M,* Li W, Li Y, Wang Q, Li C, Liu Y, Yin J, Yang X, Huang H, Chen T Q.* Discovery of an Oxidative System for Radical Generation from Csp(3)- H Bonds: A Synthesis of Functionalized Oxindoles. The Journal of Organic Chemistry, 2021, 86, 15544-15557.

[40] Tian Z, Gong Q, Huang T, Liu L, Chen T Q.* Practical Electro-Oxidative Sulfonylation of Phenols with Sodium Arenesulfinates Generating Arylsulfonate Esters. The Journal of Organic Chemistry, 2021, 86, 15914-15926.

[41] Long Liu, Yuanyuan Tang, Kunyu Wang, Tianzeng Huang, Tieqiao Chen.* Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bonds Formation via C-N Cleavage of Benzyl Ammonium Salts. The Journal of Organic Chemistry, 2021, 86, 4159-4170.

[42] Xu K Q, Liu L, Li Z H, Huang T Z, Xiang K, Chen T Q.* Controllable Phosphorylation of Thioesters: Selective Synthesis of Aryl and Benzyl phosphoryl compounds. The Journal of Organic Chemistry, 2020, 85, 14653-14663.

[43] Huang T, Chen T Q,* Han L-B.* Oxidative Dephosphorylation of Benzylic Phosphonates with Dioxygen Generating Symmetrical trans-Stilbenes. The Journal of Organic Chemistry, 2018, 83, 2959-2965.

[44] Zhang M-Z,* Luo N, Long, R-Y, Gou X-T, Shi W-B, He S-H, Jiang Y, Chen J-Y, Chen, T Q.* Transition-Metal-Free Oxidative Aminooxyarylation of Alkenes: Annulations toward Aminooxylated Oxindoles. The Journal of Organic Chemistry, 2018, 83, 2369-2375.

[45] Yang J, Xiao J, Chen T Q,* Han L-B.* Nickel-Catalyzed Phosphorylation of Phenol Derivatives via C-O/P-H Cross Coupling. The Journal of Organic Chemistry, 2016, 81, 3911-3916.

[46] Liu K, Song B, Dang Q, Liu L,* Tang J, Huang T, Li C, Tang Z, Chen T Q*. Walking Cations: Transition-Metal Free Benzyl Cation-Triggered sp2C-H Phosphorylation and Etherification. Chinese Journal of Chemistry, 2022, 40, 2933-2938.

[47] Zhang L, Liu L, Huang T, Dong Q,* Chen T Q.* Palladium-Catalyzed Cyclobutanation of Aryl Sulfonates through both C–O and C–H Cleavage. Organometallics, 2020, 39, 11, 2189-2196.

[48] Yang J, Chen T Q,* Zhou Y B, Yin S F, Han L-B.* Mechanistic Studies on the Palladium Catalyzed Cross Dehydrogenative Coupling of P(O)-H Compounds with Terminal Alkynes: Stereochemistry and Reactive Intermediates. Organometallics, 2015, 34, 5095-5098.

[49] Li C Y, Chen T Q,* Han L-B.* Iron-Catalyzed Clean Dehydrogenative Coupling of Alcohols with P(O)-H Compounds: a New Protocol for ROH Phosphorylation. Dalton Transactions, 2016, 45, 14893-14897.

[50] Chen T Q, Zhang J-S, Han L-B.* Dehydrogenative Coupling Involving P(O)-H Bonds: a Powerful Way for the Preparation of Phosphoryl Compounds. Dalton Transactions, 2016, 45, 1843-1849.

[51] Li X, Chen T Q,* Saga Y, Han L-B.* Iron-Catalyzed Cross Coupling of P-H/C-O Bonds: Efficient Synthesis of α-Alkoxyphosphorus Compounds. Dalton Transactions, 2016, 45, 1877-1880.

[52] Zhang J-S, Liu L, Chen T Q,* Han L-B, Transition Metal-Catalyzed Three-Component Difunctionalization of Alkenes, Chemistry – an Asian Journal, 2018, 13, 2277-2291.

[53] Liu C,* Xing Y-Y, Zhou T, Chen, T Q,* Hong X,* Szostak M.* Carboxylic-Phosphoric Anhydrides as Direct Electrophiles for Decarbonylative Hirao Cross-Coupling of Carboxylic Acids: DFT Investigation of Mechanistic Pathway. Chemistry- An Asian Journal, 2023, DOI: 10.1002/asia.202201262.

[54] Jin H, Gu C, Xiao Z, Tan Q, Liu L, Han L-B,* Chen W-H, Chen T Q,* Highly Chemoselective Reduction of Phosphine Oxides through Electrophilic Activation of the P=O Bond with Anhydride. European Journal of Organic Chemistry, 2023, DOI: 10.1002/ejoc.202300397.

[55] Zhang J-S, Chen T Q,* Han L-B.* Palladium-Catalyzed Direct Decarbonylative Phosphorylation of Benzoic Acids with P(O)-H Compounds. European Journal of Organic Chemistry, 2020, 2020, 1148-1153.

[56] Zhang S, Yang L, Fu J, Tan Q, Liu K, Huang T*, Li C, Liu L, Chen T Q*. Palladium-catalyzed and Norbornene-mediated C-H Amination and C-O Alkenylation of Aryl Triflates. Organic & Biomolecular Chemistry, 2023, DOI: 10.1039/D3OB00260H.

[57] Liu K, Ding D, Xing W, Liu L,* Zhang S, Meng Q, Chen T Q,* Palladium catalysed deaminative/decarboxylative cross-coupling  of organoammonium salts with carboxylic acids, Organic & Biomolecular Chemistry, 2023, doi: 10.1039/D2OB02251F

[58] Zhang T, Wang K, Ke Y, Tang Y, Liu L,* Huang T, Li C, Tang Z, Chen T Q.* Transition-metal-free and base promoted C-C bond formation via C-N bond cleavage of organoammonium salts. Organic & Biomolecular Chemistry, 2021, 19, 8237-8240.

[59] Ye R Z, Cao Y J, Xi X X, Liu L, Chen T Q.* Metal- and radical-free aerobic oxidation of heteroaromatic methanes: an efficient synthesis of heteroaromatic aldehydes. Organic & Biomolecular Chemistry, 2019, 17, 4220-4224.

[60] Zhang M-Z,* Wang X, Gong M-Y, Chen L, Shi W-B,* He S-H, Jiang Y, Chen T Q.* An efficient iodine pentoxide-triggered iodocarbocyclizations for the synthesis of iodooxindoles in water. Organic & Biomolecular Chemistry, 2018, 16, 5197-5202.

[61] Chen L, Zhu Y Y, Chen T Q,* Liu L, Zhang J-S, Han L-B.* Direct C-OH/P(O)-H Dehydration Coupling Forming Phosphine Oxides. Organic & Biomolecular Chemistry, 2018, 16, 5090-5093.

[62] Zhang J-S, Zhang J-Q, Chen T Q,* Han L-B.* t-BuOK-Mediated Reductive Addition of P(O)-H Compounds to Terminal Alkynes Forming β-Arylphosphine oxides. Organic & Biomolecular Chemistry, 2017, 15, 5462-5467.

[63] Liu M, Chen X, Chen T Q,* Yin S F.* Facile and General Acid-Catalyzed Deuteration at Methyl Groups of N-Heteroarylmethanes. Organic & Biomolecular Chemistry, 2017, 15, 2507-2511.

[64] Liu M, Chen X, Chen T Q,* Xu Q, Yin S F.* Metal-Free Oxidative para-Acylation of Unprotected Anilines with N-Heteroarylmethanes. Organic & Biomolecular Chemistry, 2017, 15, 9845-9854.

[65] Huang Y, Chen T Q,* Li Q, Zhou Y B, Yin S F.* Copper Catalysed Direct Amidation of Methyl Groups with N-H Bonds. Organic & Biomolecular Chemistry, 2015, 13, 7289-7293.

[66] Lin Y, Li D, Zhang J, Tang Z,* Liu L, Huang T, Li C, Chen T Q.* I-2/NaH2PO2-mediated deoxyamination of cyclic ethers for the synthesis of N-aryl-substituted azacycles. New Journal of Chemistry, 2021, 45, 21011-21014.

[67] Cao Y, Liu L, Huang T, Chen T Q.* Iodine-catalyzed ,-dehydrogenation of ketones and aldehydes generating conjugated enones and enals. New Journal of Chemistry, 2020, 44, 8697-8701.

[68] Wang Q, Liu L, Dong J,* Chen T Q.* Metal-free thioesterification of amides generating acyl thioesters. New Journal of Chemistry, 2019, 43, 9384-9388.

[69] Xiao J, Yang J, Chen T Q,* Han L-B.* Nickel-Catalyzed α-Benzylation of Sulfones with Esters via C-O Activation. RSC Advances, 2016, 6, 42656-42659.

[70] Li S, Chen T Q,* Saga Y, Han L-B.* Chloroform-Based Atherton-Todd-Type Reactions of Alcohols and Thiols with Secondary Phosphine Oxides Generating Phosphinothioates and Phosphinates. RSC Advances, 2015, 5, 71544-71546.

[71] Chen T Q,* Tan Q, Liu L, Huang T, Han L-B.* Phosphorylation of Carboxylic Acids and Their Derivatives with P(O)–H Compounds Forming P(O)–C Bonds. Synthesis, 2020, 52, A-L.

[72] Chen T Q, Han L-B.* Optically Active H-Phosphinates and Their Stereospecific Transformations to Optically Active P-Stereogenic Organophosphoryl Compounds. Synlett, 2015, 26, 1153-1163.

[73] Huang T-Z, Chen T Q,* Saga Y, Han L-B.* Me3P-catalyzed addition of hydrogen phosphoryl compounds P(O)H to electron-deficient alkenes: 1 to 1 vs 1 to 2 adducts. Tetrahedron, 2017, 73, 7085-7093.

[74] Xu T, Zhou X, Han Y, Zhang L, Liu L, Huang T, Li C, Tang Z, Wan S,* Chen T Q.* Palladium-catalyzed stereo-selective three-component cis-1,2-arylalkynylation of bicyclic alkenes with aryltriflates and terminal alkynes. Tetrahedron Letters, 2022, 97, 153799.

[75] Liu L, Yu W-Q, Huang T, Chen T Q.* Palladium-catalyzed alkynylation of aromatic amines via in situ formed trimethylammonium salts. Tetrahedron Letters, 2020, 61, 151647.

[76] Liu L, Xu K, Wang Y, Wang W., Xu H, Huang T, Chen T Q.* Palladium-catalyzed phosphorylation of benzyl ammonium triflates with P(O)H compounds. Tetrahedron, 2020, 76, 131020.

[77] Yang J, Xiao J, Chen T Q,* Han L -B.* Nickel-Catalyzed Phosphorylation of Aryl Triflates with P(O)-H Compounds. Journal of Organometallic Chemistry, 2016, 820, 120-124.

[78] Chen T Q, Xiao J, Zhou Y B, Yin S F, Han L -B.* Nickel-Catalyzed (E)-Selective Semihydrogenation of Internal Alkynes with Hypophosphorous Acid. Journal of Organometallic Chemistry, 2014, 749: 51-54.

[79] Xiao J, Li Q, Chen T Q,* Han L -B.* Copper-Mediated Selective Aerobic Oxidative C3-Cyanation of Indoles with DMF. Tetrahedron Letters, 2015, 56, 5937-5940.

[80] Lei J,† Su L B,† Zeng K,† Chen T Q,† Qiu R H, Zhou Y B, Au C-T, Yin S F,* Recent advances of catalytic processes on the transformation of alkynes into functional compound. Chemical Engineering Science, 2017, 171, 404-425 (†:First co-author).

[81] Chen T Q, Zhou Y B, Guo C C,* Han L -B.* Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-Bound Triphenylphosphine. Chemistry Letters, 2013, 42, 1065-1067.

[82] Chen T Q, Zhou Y B, Yin S-F, Zhao Y L, Goto M, Han L -B.* Identification of Alkenyl and Arylpalladium Hydrides by the Aid of Hydrosilanes. Chemistry Letters, 2013, 42, 1227-1229.

[83] Yang J, Xiao J, Zhou Y B,* Chen T Q,* Yin S F, Han L-B.* Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds. Chinese Journal of Organic Chemistry, 2017, 37, 1055-1068.

[84] Chen T Q, Liu L, Huang T, Han L-B. Synthesis and Reactivity of Group 10 Transition Metal Complexes with Alkenylphosphoryl Compounds. Chinese Journal of Organic Chemistry, 2019, 39, 2183-2187.

[85] Chen T Q, Han L-B.* Oxidative Addition of (RO)2P(O)H to Pt(0) Complexes Generating Pt-H Complexes: P(O)-H Bond Cleavage vs P(O-H) Bond Cleavage. Heteroatom Chemistry, 2018, e21460.

[86] Zhao Y L, Chen T Q,* Wang X B, Han L-B.* A Convenient Stereoselective Reduction of gem-Dibromides with a Combination of Dimethyl Phosphite and Potassium Carbonate. Phosphorus, Sulfur, and Silicon and the Related Elements, 2015, 190, 1820-1827.

1. 陈铁桥，徐添豪，刘龙，黄添增，唐智，李春娅。一类芳基腈类化合物及其制备方法。发明专利号202210214551.2，专利公开日期：2022.05.24，已授权。

2. 陈铁桥，徐添豪，刘龙，黄添增，唐智，李春娅。一类芳基硫醚类化合物及其制备方法。发明专利号CN202111168584.X，专利公开日期：2021.11.26。

3. 陈铁桥，靳洪宇，岑梦洁，刘龙，黄添增，唐智，李春娅。一种膦（Ⅲ）类化合物的合成方法。发明专利号 202111138716.4，专利公开日期：2021.11.26。

4. 陈铁桥，李昕怡，刘龙，黄添增，唐智，李春娅。一类芳基炔烃类化合物及其制备方法。发明专利号 202110741126.4，专利公开日期：2023.01.03。

合作交流:

[1] Chen T Q, 酸/碘协同催化惰性酰胺的转氨化反应，中国化学会第33届学术年会，山东，青岛，2023.6.17-2023.6.20 (oral talk).

[2] Chen T Q, 酸/碘协同催化惰性酰胺的转氨化反应，第二届中国化工学会精细化工大会，辽宁，大连，2023.7.23-2023.7.25 (oral talk).

[3] Chen T Q, Highly Chemoselective Transamidation of Unactivated Tertiary Amides via Acid/Iodide Cooperative Catalysis, 16th International Symposium for Chinese Organic Chemists (ISCOC)，北京，2023.8.27-2023.8.31 (oral talk).

[4] 陈铁桥，有机磷化合物的绿色合成，大连理工大学，包明课题组，2023.7.24

[5] 陈铁桥，有机磷化合物的绿色合成，福建农林大学，郭梨锦课题组，2022.11.11.

[6] 陈铁桥，有机磷化合物的绿色合成，新疆大学，刘晨江课题组，2022.11.23.

[7] Chen T Q，酸/碘协同催化惰性酰胺的转氨化反应，精细化工国际学术研讨会，湖南，岳阳，2022.11.6-2022.11.10 (邀请报告).

[8] Chen T Q，立体选择性合成烯基磷化合物，第十届岭南有机化学论坛，广东，广州，2021.11.19-2021.11.22 (邀请报告).

[9] Chen T Q，脱氢策略合成有机磷化合物，中国化学会第32届学术年会，广东，珠海，2021.4.18-2021.4.22 (oral talk).

[10] Chen T Q, 脱氢策略合成有机磷化合物，永利集团人事处，海南，海口，2021.3.30 (Invited talk).

[11] Chen T Q，脱氢策略合成有机磷化合物，第二届热带海洋资源利用与绿色化工研讨会，永利集团，海南，海口，2020.02.20 (oral talk).

[12] Chen T Q，脱氢策略合成有机磷化合物，第三届中南有机化学论坛，海南师范大学，海南，海口，2019.11.09 (大会报告).

[13] Chen T Q，过渡金属催化磷酸化：绿色合成有机磷化合物，第二届中南有机化学论坛，广西师范学院，广西化学化工学会，广西民族大学，南宁，中国，2018.11.09-2018.11.11 (invited talk).

[14] Chen T Q，绿色合成有机磷化合物，第八届岭南有机化学论坛，广西师范大学，桂林，中国，2018.10.11-2018.10.13 (invited talk).

[15] Chen T Q, 基于Z-H键转化的绿色合成及其机理研究, 2017年海南省化学化工学科论坛与发展研讨会。海南师范大学,海口,中国, 2017.11.18-2017.11.19 (invited talk).

[16] Chen T Q, 过渡金属催化C-Z/P-H（Z = O,S,CN）交叉偶联构建C-P键，第十一届全国磷化学化工学术讨论会. 武汉, 2017.10.21-2017.10.23 (invited talk).

[17] Chen T Q, 过渡金属催化C-O键活化构建C-Z键，第十五届全国均相催化学术讨论会. 杭州, 2017.9.26-2017.9.29 (Oral Talk).

[18] Chen T Q. 过渡金属催化脱氢偶联反应合成有机磷化合物，一带一路绿色化学高端论坛，兰州，2017年7月14日-16日 (Poster).

[19] Chen T Q, Yoshimura A, Han L-B. Ni-catalyzed C-O/Z-H cross coupling forming C-Z bonds. International Symposium on C-O activation (ISCO-2016). Himeji, Hyogo, Japan, 2016.10.25-2016.10.27 (Oral Talk).

[20] Chen T Q, Han L-B. Synthesis of organophosphorus compounds via metal-catalyzed dehydrogenative couplings. The 43rd Symposium on Main Group Element Chemistry. Sendai, Japan, 2016.12.08-2016.12.10 (Poster).

[21] Chen T Q. 基于Z-H键转化的绿色合成及其机理研究. 海南师范大学,海口,中国, 2016.10.15 (Oral Talk).