研究方向:
1. 多酸基复合材料在催化中的应用探索;2. 多酸基金属有机框架的设计、合成与应用;3. 晶态多酸基智能材料的制备与应用研究。
科研项目:
1. 永利集团科研启动经费,永利集团刺激响应型多酸功能化的超分子聚合物的合理设计和应用研究,项目负责人。
论著专利:
一、期刊论文
1. Shenzhen Chang, Yanhong Chen, Haiyan An, Qingshan Zhu, Huiyun Luo, and Yaohui Huang. Polyoxometalate-Based Supramolecular Porous Frameworks with Dual-Active Centers towards Highly Efficient Synthesis of Functionalized p-Benzoquinones. Green Chem., 2021, 23, 8591−8603;
2. Shenzhen Chang, Yanhong Chen, Haiyan An, Qingshan Zhu, Huiyun Luo, and Tieqi Xu. Highly Efficient Synthesis of p-Benzoquinones Catalyzed by Robust Two-Dimensional POM-Based Coordination Polymers. ACS Appl. Mater. Interfaces, 2021, 13, 21261−21271;
3. Shenzhen Chang, Haiyan An, Yanhong Chen, Yujiao Hou, Jie Zhang, and Qingshan Zhu. Multiunit Catalysts with Synergistic Reactivity: Three-Dimensional Polyoxometalate-Based Coordination Polymers for Highly Efficient Synthesis of Functionalized p-Benzoquinones. ACS Appl. Mater. Interfaces, 2019, 11, 37908−37919;
4. Shenzhen Chang, Haiyan An, Yanhong Chen, Qingshan Zhu, Huiyun Luo, and Yaohui Huang. Highly Efficient Supramolecular Catalysts Assembled by Dawson-Type POMs and Metal–Organic Complexes for the Synergistic Catalytic Synthesis of p-Benzoquinones. ACS Sustainable Chem. Eng.,2022, 10, 4728−4740.
5. Yanhong Chen, Shenzhen Chang, Haiyan An, Yanqin Li, Qingshan Zhu, Huiyun Luo, and Yaohui Huang. Two Polymorphic Polyoxometalate-Based Metal–Organic Frameworks for the Efficient Synthesis of Functionalized Sulfoxides and Detoxification of Mustard Gas Simulants. ACS Sustainable Chem. Eng.,2021, 9, 15683−15693;
6. Yanhong Chen, Haiyan An, Shenzhen Chang, Yanqin Li, Tieqi Xu, Qingshan Zhu, Huiyun Luo, Yaohui Huang, and Yuting Wei. Two pseudo-Polymorphic Porous POM-Pillared MOFs for Sulfide-Sulfoxide Transformation: Efficient Synergistic Effects of POM Precursors, Metal Sites and Microstructures. Chin. Chem. Lett., 2023, 34, 107856;
7. Yanhong Chen, Haiyan An, Shenzhen Chang, Yanqin Li, Huiyun Luo, and Yaohui Huang. A POM-Based Porous Supramolecular Framework for Efficient Sulfide-Sulfoxide Transformations with a Low Molar O/S Ratio. Inorg. Chem. Front.,2022, 9, 3282−3294;
8. Haiyan An, Yujiao Hou, Shenzhen Chang, Jie Zhang, and Qingshan Zhu. Highly Efficient Oxidation of Various Thioethers Catalyzed by Organic Ligand-Modified Polyoxomolybdates. Inorg. Chem. Front.,2020, 7, 169−176;
9. Yanhong Chen, Haiyan An, Shenzhen Chang, Tieqi Xu,* Yanqin Li, Qingshan Zhu, Yaohui Huang, and Yuting Wei. Visible-Light-Responsive 2D Photocatalysts Assembled by Evans−Showell-Type POMs and Metalloviologen Frameworks for Sulfide−Sulfoxide Transformation. Inorg. Chem., 2023, 62, 10120−10130;
10. Haiyan An, Jie Zhang, Shenzhen Chang, Yujiao Hou, and Qingshan Zhu. 2D Hybrid Architectures Constructed from Two Kinds of Polyoxovanadates as Efficient Heterogeneous Catalysts for Cyanosilylation and Knoevenagel Condensation. Inorg. Chem., 2020, 59, 10578−10590;
11. Yanhong Chen, Longhui Sun, Shenzhen Chang, Lijuan Chen, and Junwei Zhao. Synergistic Effect between Different Coordination Geometries of Lanthanides and Various Coordination Modes of 2-Picolinic Acid Ligands Tuning Three Types of Rare 3d-4f Heterometallic Tungstoantimonates. Inorg. Chem,2018, 57, 15079−15092;
12. Yujiao Hou, Haiyan An, Shenzhen Chang, and Jie Zhang. Versatile Catalysts Constructed from Hybrid Polyoxomolybdates for Simultaneously Detoxifying Sulfur Mustard and Organophosphate Simulants. Catal. Sci. Technol.,2019, 9,2445−2455;
13. Haiyan An, Huiyun Luo, Tieqi Xu, Shenzhen Chang, Yanhong Chen, Qingshan Zhu, Yaohui Huang, Huaqiao Tan, and Yang-Guang Li. Visible-Light-Driven Oxidation of Amines to Imines in Air Catalyzed by Polyoxometalate-Tris(bipyridine)ruthenium Hybrid Compounds. Inorg. Chem.,2022, 61, 10442−10453;
14. Yujiao Hou, Haiyan An, Yumeng Zhang, Tao Hu, Wei Yang, and Shenzhen Chang. Rapid Destruction of Two Types of Chemical Warfare Agent Simulants by Hybrid Polyoxomolybdates Modified by Carboxylic Acid Ligands. ACS Catal.,2018, 8, 6062−6069;
15. Haiyan An, Yujiao Hou, Lin Wang, Yumeng Zhang, Wei Yang, and ShenZhen Chang. Evans-Showell-Type Polyoxometalates Constructing High-Dimensional Inorganic-Organic Hybrid Compounds with Copper-Organic Coordination Complexes: Synthesis and Oxidation Catalysis. Inorg. Chem.,2017, 56, 11619−11632;
16. Haiyan An, Yumeng Zhang, Yujiao Hou, Tao Hu, Wei Yang, Shenzhen Chang, and Jianjun Zhang. Hybrid Dimers Based on Metal-Substituted Keggin Polyoxometalates (Metal = Ti, Ln) for Cyanosilylation Catalysis. Dalton Trans.,2018, 47, 9079−9089.
二、专利
1 安海艳,常深圳.一类多酸基金属有机框架晶体材料、制备方法及其催化合成对苯醌类化合物的应用. ZL201910641308.7, 2021 (已授权)。