研究方向:
1)分子基磁性材料的构筑、表征及应用;
2)多孔金属有机框架材料(MOFs)的合成及性能研究;
3)高能密度材料的制备及理化性能研究。
讲授课程:
主讲《无机化学》、《分析化学》、《无机化学实验》、《分析化学实验》等
学术成就:
理学博士,博士后,副教授,博士生导师,海南省D类高层次人才。从事于分子基磁体的化学与物理、金属有机框架基含能材料的化学与物理的研究,主持国家级、省部级项目10余项。在Coordination Chemistry Reviews, Chemical Communications, Inorganic Chemistry, SCIENCE CHINA Chemistry, Journal of Materials Chemistry A等主流学术期刊上发表SCI论文60余篇,其中以第一作者或通讯作者发表文章30余篇(中国科学院SCI分区:一区9篇,二区14篇,三区5篇,四区2篇)。 2024年,海南省高校精品在线开放课程负责人《分析化学实验》;2023年,荣获“第三届全国高校教师教学创新大赛海南赛区比赛”二等奖(排名第一);2022年,荣获“第二届全国高校教师教学创新大赛海南赛区比赛”二等奖(排名第二);2022年,指导员工荣获全国老员工化学实验创新设计大赛一等奖(国家级,2022-总决赛-T029);2023年,指导员工荣获海南省高等学校第三届老员工化学实验技能竞赛一等奖、二等奖各一项。
科研项目:
1. 国家自然科学基金地区基金项目,22363004,2024.01-2027.12,主持;
2. 国家自然科学基金青年基金项目,21703002,2018.01-2020.12,主持;
3. 海南省科技厅自然科学基金-青年基金项目,222QN223,2022.04-2025.03,主持;
4. 海南省自然科学基金高层次人才项目,123RC396,2023.03-2026.02,主持;
5. 海南省高等学校公司产品改革项目,Hnjg2022-29,2022.01-2024.12,主持;
6. 陕西省教育厅专项科学研究计划项目,20JK0484,2020.01.01-2021.12.31,主持;
7. 陕西省高校科协青年人才托举计划项目,20200610,2020.01.01-2022.12.31,主持;
8. 陕西省科技厅自然科学基础研究计划-一般项目(青年),2019JQ-180, 2019.01.01-2020.12.31,主持;
9. 第61批中国博士后科学研究基金项目,2017M610646,一等资助,2017.6- 2018.2,主持;
10. 陕西省博士后基金项目,一等资助,2017.6-2018/7,主持;
11. 西北大学合成与天然功能分子化学教育部重点实验室开放基金项目,338050067(2018-008),2018.11-2020.11,主持;
12. 指导老员工创新训练计划,国家级2项;
13. 永利集团高层人才项目,KYQD(ZR)21141,校级。
论著专利:
2024/2023年
(1) Yangyang Gou,‡ Ming Gao,‡ Yunlong Wu, Wei Zhou, Jiancheng Feng, Sheng Zhang,* Xiaohong Wang,* Bing Yin,* Construction of porous 2D Dy3+ metal organic frameworks: solvent responsive magnetic dynamics under 0 Oe dc field and luminescent sensors for Fe3+ ions, CrystEngComm, 2024, 26, 4057-4072.
(2) Jiamin Tang, Sheng Zhang,* Linzhou Li, Linbin Yao, Ronghu Zhang, Bing Yin, Jiangwei Zhang, Influence of ligand substitution and the solvent effect on the structures and magnetic properties of dinuclear Dy2 supramolecular architectures constructed with the bis-β-diketonate-Dy2 building block as a metalloligand, Dalton Transactions, 2023, 52, 1366-1377.
2022年
(1) Sheng Zhang*, Jiamin Tang, Linzhou Li, Linbin Yao, Ronghu Zhang*, Bing Yin*, Theoretical and experimental studies of the magnetostructural correlations in mononuclear DyIII compounds evidenced by quantum tunneling of magnetization time, crystal field parameters, and point charge electrostatic model, Crystal Growth & Design, 2022, 22, 5459-5471.
(2) Fang Xu, Jin Zhang, Hongxi Gu, Rong Ma, Sheng Zhang*, Jiancheng Feng,* Bing Yin,* Influence of synthesis conditions on the preparation of mononuclear Dy(III) compounds based on β-diketone ligands: Synthesis, structure, magnetic behavior and theoretical analysis, Journal of Solid State Chemistry, 2022, 305, 122686.
2021年
(1) Sheng Zhang,* Jiamin Tang, Jin Zhang, Fang Xu, Sanping Chen, Dengwei Hu, Bing Yin, Jiangwei Zhang, In Situ ligand formations in the synthetic processes from mononuclear Dy (III) compounds to binuclear Dy (III) compounds: synthesis, structure, magnetic behavior and theoretical analysis, Inorganic Chemistry, 2021, 60, 816–830.
(2) Sheng Zhang,* Nan Shen, Jiangwei Zhang, Fang Xu, Jin Zhang, Jiamin Tang, Dengwei Hu, Bing Yin, Sanping Chen, Solvent responses and substituent effects upon magnetic properties of mononuclear DyIII compounds, Dalton Transactions, 2021, 50, 624-637.
(3) Nan shen, Jing liang, Xiaoni Qu, Sha Liu, Lin zhu, Sheng Zhang,* Ling chen, Jiangwei Zhang, Dengwei Hu, Bing Yin, The influence of organic bases and substituted groups upon coordination structures affording two mononuclear Dy (III) single-molecule magnets (SMMs) and a novel Dy (III)-K (I) compound with unusual coordinated fluorine atoms, CrystEngComm, 2021, 23, 4013-4027.
2020年
(1) Sheng Zhang,* Nan Shen, Sha Liu, Rong Ma, Yi-Quan Zhang, Deng-Wei Hu, Xiang-Yu Liu, Jiang-Wei Zhang and De-Suo Yang, Rare CH3O−/CH3CH2O−-bridged nine-coordinated binuclear DyIII single-molecule magnets (SMMs) significantly regulate and enhance the effective energy barriers, CrystEngComm, 2020, 22(8), 1712-1724.
(2) Desuo Yang, Wenjiao Mo, Sheng Zhang,* Bing Li, Dengwei Hu, Sanping Chen, Graphene oxide functionalized energetic coordination polymer possesses good thermostability, heat release and combustion catalytic performance for ammonium perchlorate, Dalton Transactions, 2020, 49(5), 1582-1590.
2019年
(1) Sheng Zhang,* Wenjiao Mo, Jiangwei Zhang, Zengqi Zhang, Bing Yin,* Dengwei Hu, and Sanping Chen,* Regulation of Substituent Effects on Configurations and Magnetic Performances of Mononuclear DyⅢ Single-Molecule Magnets, Inorganic Chemistry, 2019, 58 (22), 15330-15343.
(2) Sheng Zhang, Wenjiao Mo, Zengqi Zhang, Fei Gao, Lei Wang, Dengwei Hu, Sanping Chen, Ligand ratio/solvent-influenced syntheses, crystal structures, and magnetic properties of polydentate Schiff base ligand-Dy(III) compounds with β-diketonate ligands as co-ligands, Dalton Transactions, 2019, 48, 12466-12481.
(3) Sheng Zhang,* Wenjiao Mo, Bing Yin,* Xingqiang Lü and Jiangwei Zhang,* Designing a mononuclear DyⅢ single-molecule magnet (SMM) by using a N,O,N,O-based multichelating Schiff base ligand and a β-diketonate ligand, New Journal of Chemistry, 2019, 43(1), 454-462.
(4) Sheng Zhang, Shuo Wu, Wendou Zhang, Qi Yang, Qing Wei, Gang Xie, Sanping Chen, Shengli Gao, Jack Y. Lu, 3D solvent-free energetic metal–organic framework (EMOF) achieved by removing inclusion molecules from a new coordination polymer, CrystEngComm, 2019, 21, 583-588.
2018年
(1) Sheng Zhang,* Wenjiao Mo, Bing Yin,* Gaini Zhang, Desuo Yang,* Xingqiang Lü, Sanping Chen,* The slow magnetic relaxation regulated by the coordination, configuration and intermolecular dipolar field in two mononuclear DyⅢ singlemolecule magnets (SMMs), Dalton Transactions, 2018, 47(35), 12393-12405.
(2) Sheng Zhang, Xiaxia Song, Guowei Lin, Qi Yang, Quan Shi, Hui Zheng, Xin Liu, Qing Wei, Gang Xie, Sanping Chen, Shengli Gao, Low temperature heat capacity and magnetic property of two H2ZTO-Co (II) coordination polymers (H2ZTO = 4,4’-azo-1,2,4-triazol-5-one), The Journal of Chemical Thermodynamics, 2018, 125, 214–219.
(3) Sheng Zhang,* Wenjiao Mo, Jiangwei Zhang, Haipeng Wu, Min Li, Xingqiang Lü, Bing Yin,* Desuo Yang,* Experimental and theoretical interpretation of the magnetic behavior of two Dy(Ⅲ) single-ion magnets constructed through β-diketonate ligands with different substituent groups (-Cl/-OCH3), RSC Advances, 2018, 8(52), 29513-29525.
2017年
(1) Sheng Zhang, Haipeng Wu, Lin Sun, Hongshan Ke, Sanping Chen, Bing Yin, Qing Wei, Desuo Yang, Shengli Gao, Ligand Field Fine-tuning on Modulation of Magnetic Properties and Relaxation Dynamics for Dysprosium (III) Single-Ion Magnets (SIMs):Synthesis, Structure, Magnetism and Ab Initio Calculations, Journal of Materials Chemistry C, 2017, 5(6): 1369-1382.
2016年
(1) Sheng Zhang, Hongshan Ke, Quan Shi, Jangwei Zhang, Qi Yang, Qing Wei, Gang Xie, Wenyuan Wang, Desuo Yang, Sanping Chen, Dysprosium(III) Complexes with a Square-Antiprism Configuration Featuring Mononuclear Single-Molecule Magnetic Behaviours based on Different β-Diketonate Ligands and Auxiliary Ligands, Dalton Transactions, 2016, 45(12): 5310-5320.
(2) Sheng Zhang, Hongshan Ke, Lin Sun, Xin Li, Quan Shi, Gang Xie, Qing Wei, Desuo Yang, Wenyuan Wang, Sanping Chen, Magnetization Dynamics Changes of Dysprosium (III) Single-Ion Magnets Associated with Guest Molecules, Inorganic Chemistry, 2016, 55(8): 3865-3871.
(3) Sheng Zhang, Qi Yang, Xiangyu Liu, Xiaoni Qu, Qing Wei, Gang Xie, Sanping Chen, Shengli Gao. High-Energy Metal-Organic Frameworks (HE-MOFs): Synthesis, Structure and Energetic Performance, Coordination Chemistry Reviews, 2016, 307(2): 292-312.
2015年
(1) Sheng Zhang, Hongshan Ke, Xiangyu Liu, Qing Wei, Gang Xie, Sanping Chen. A Nine-Coordinated Dysprosium(III) Compound with Oxalate-Bridged Dysprosium(III) Layer Exhibiting two Slow Magnetic Relaxation Processes, Chemical Communications, 2015, 51(82): 15188-15191.
(2) Sheng Zhang, Xiangyu Liu, Bin Liu, Zhengqiang Xia, Weitao Wang, Qi Yang, Hongshan Ke, Qing Wei, Gang Xie, Sanping Chen, Shengli Gao, 3D Co(II, III) Mixed-Valence Metal-Organic Framework Affording Field-Induced Slow Magnetic Relaxation, SCIENCE CHINA Chemistry, 2015, 58(6): 1032-1038.
(3) Sheng Zhang, Xiangyu liu, Qi Yang, Qing Wei, Gang Xie, Sanping Chen.* Mixed metal organic frameworks (M′MOFs) from 1D to 3D based on the “organic” connectivity and the inorganic connectivity: syntheses, structures and magnetic properties, CrystEngComm, 2015, 17, 3312–3324.
2014年
(1) Sheng Zhang, Xiangyu Liu, Qi Yang, Zhiyong Su, Wenjuan Gao, Qing Wei, Gang Xie, Sanping Chen, Shengli Gao, A New Strategy for Storage and Transportation of Sensitive High Energy Materials: Guest-Dependent Energy and Sensitivity of 3D Metal–Organic-Framework-based Energetic Compounds, Chemistry-A European Journal, 2014, 20(26): 7906-7910.
(2) Sheng Zhang, Yang Yang, Zhengqiang Xia, Xiangyu Liu, Qi Yang, Qing Wei, Gang Xie, Sanping Chen, Shengli Gao, Eu-MOFs with 2(4-Carboxyphenyl)imida[4,5f]1, 10-phenanthroline and Ditopic Carboxylates as Coligands: Synthesis, Structure, High Thermostability and Luminescence Properties, Inorganic Chemistry, 2014, 53(20): 10592-10563.
(3) Sheng Zhang, Qing Wei, Xiangyu Liu, Qi Yang, Gang Xie, Sanping Chen, Water-induced Reversible Dissolution/Reorganization Transformations of Cu(II)-K(I) Heterometallic Coordination Polymers, SCIENCE CHINA Chemistry, 2014, 57(9): 1225-1234.